Discovery and development of microporous metal carboxylates.
Discovery and development of microporous metal carboxylates.
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DOI：
10.1002/tcr.20060
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发表时间：
2005
期刊：
影响因子：
6.6
通讯作者：
W. Mori;Tomohiko Sato;C. Kato;T. Takei;T. Ohmura
中科院分区：
文献类型：
--
作者：
W. Mori;Tomohiko Sato;C. Kato;T. Takei;T. Ohmura
我们已经发现了一种形式的对苯二甲酸铜（II），它吸留了大量的气体，如N2，Ar，O2和CO2。对苯二甲酸铜（II）是发现的第一种能够吸附气体的金属络合物。该配合物开辟了吸附化学的新领域，被公认为微孔金属配合物构建的领导者。在扩展微孔复合物的合成路线中，我们获得了许多新的多孔材料，这些材料被广泛认为是在气体储存、分子筛、催化、包合物和表面科学等领域中应用的有用材料。
We have found a form of copper(II) terephthalate that occluded an enormous amount of gases such as N2, Ar, O2, and Xe. Copper(II) terephthalate is the first metal complex found capable of adsorbing gases. This complex has opened a new field of adsorbent chemistry and is recognized as a leader in the construction of microporous metal complexes. In extending the route for the synthesis of microporous complexes, we obtained many new porous materials that are widely recognized as useful materials for applications in areas such as gas storage, molecular sieves, catalysis, inclusion complexes, and surface science.