<i>N</i>-Acylimino-λ<sup>3</sup>-iodanes from the Metathesis of Iodosoarenes and Nitriles for the Photoinduced C?H Perfluoroacylamination of (Hetero)Arenes
<i>N</i>-Acylimino-λ<sup>3</sup>-iodanes from the Metathesis of Iodosoarenes and Nitriles for the Photoinduced C?H Perfluoroacylamination of (Hetero)Arenes
复制标题
来自碘代芳烃和腈的复分解的<i>N</i>-酰基亚氨基-λ<sup>3</sup>-碘用于（杂）芳烃的光诱导C?H全氟酰胺化
DOI：
10.1021/acs.orglett.2c02054
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发表时间：
2022
期刊：
影响因子：
5.2
通讯作者：
Kobayashi Yusuke
中科院分区：
文献类型：
--
作者：
Kimura Tomohiro;Hamada Shohei;Furuta Takumi;Takemoto Yoshiji;Kobayashi Yusuke
通过碘代芳烃和全氟烷烃腈之间的前所未有的复分解反应，实现了N-全氟酰基亚氨基-λ3-碘烷的高效和可放大的合成。碘烷的全氟酰氨基基团可以使用光辐射引入到芳环和杂芳环上。
An efficient and scalable synthesis ofN-perfluoroacylimino-λ3-iodanes was achieved via an unprecedented metathesis between iodosoarenes and perfluoroalkanenitriles. The perfluoroacylamino groups of the iodanes could be introduced to aromatic and heteroaromatic rings using photoirradiation.