Synthesis of Orthorhombic Mo-V-Sb Oxide Species by Assembly of Pentagonal Mo6O21 Polyoxometalate Building Blocks
Synthesis of Orthorhombic Mo-V-Sb Oxide Species by Assembly of Pentagonal Mo6O21 Polyoxometalate Building Blocks
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DOI：
10.1002/anie.200805792
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发表时间：
2009-01-01
影响因子：
16.6
通讯作者：
Ueda, Wataru
中科院分区：
文献类型：
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作者：
Sadakane, Masahiro;Yamagata, Keiko;Ueda, Wataru
混合搭配：五边形的[Mo6O21]n -多氧钼酸盐构建块与其他来源的Mo、V和Sb离子组装形成正交的Mo - V - Sb氧化物。首次对正交型Mo-V基氧化物（一种很有前途的轻烷烃选择性氧化催化剂，称为“M1相”）的单晶X射线分析揭示了该化合物的结构。
Mix and match: The pentagonal [Mo6O21]n−polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo‐V‐Sb oxide. The first single‐crystal X‐ray analysis of an orthorhombic Mo–V‐based oxide, a promising catalyst for light alkane selective oxidation known as the “M1 phase”, revealed the structure of the compound.