Reductive alkylation of muorinated graphite
Reductive alkylation of muorinated graphite
复制标题
DOI：
10.1021/cm800060q
复制
发表时间：
2008-05-13
影响因子：
8.6
通讯作者：
Billups, W. E.
中科院分区：
文献类型：
--
作者：
Chakraborty, Soma;Guo, Wenhua;Billups, W. E.
氟化石墨（CFx）经烷基化还原得到由6至23片石墨烯片组成的功能化石墨片。提出了一种涉及单电子转移的自由基机制。氟化底物导致的更高水平的功能化导致材料在有机溶剂中表现出更高的溶解度。
Fluorinated graphite (CFx) was alkylated reductively to yield functionalized graphite platelets comprised of six to 23 graphene sheets. A free radical mechanism involving a single electron transfer was proposed. The higher level of functionalization that resulted from the fluorinated substrate led to materials that exhibited an enhanced solubility in organic solvents.