Formation of a thiocarboxamidomolybdenum complex by oxidative bond cleavage. Crystal and molecular structure of bis[.mu.-sulfido-thiocarboxamido(dipropyldithiocarbamato)molybdenum], [MoS(SCN(C3H7)2)(S2CN(C3H7)2)]2
Formation of a thiocarboxamidomolybdenum complex by oxidative bond cleavage. Crystal and molecular structure of bis[.mu.-sulfido-thiocarboxamido(dipropyldithiocarbamato)molybdenum], [MoS(SCN(C3H7)2)(S2CN(C3H7)2)]2
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通过氧化键断裂形成硫代羧酰胺钼络合物。
DOI：
10.1021/ic50127a050
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发表时间：
1973
影响因子：
4.6
通讯作者：
R. Weiss
中科院分区：
文献类型：
--
作者：
L. Ricard;J. Estienne;R. Weiss
结论本研究的目的是研究最近在Mo2（02CCH3）4与NH4S2CN（C3H7）2反应中观察到的碳硫键断裂的普遍性。KS2COC2H5和Mo2（O2CCH3）4之间反应的主要产物现在显示具有过渡金属羧酸盐结构。然而，反应产物之一尚未完全表征。前面提到的可能成分为Mo 2 Xan 4的绿色化合物具有最令人困惑的行为。最近的研究表明，它的反应方式预期的烷氧基羰基络合物15，16和
ConclusionThe aim of this study was to investigate the generality of the carbon-sulfur bond cleavage recently observed in the reaction of Mo2 (02CCH3) 4 with NH4S2CN (C3H7) 2. The main product of the reaction between KS2COC2H5 andMo2 (02CCH3) 4 is now shown to have a transition metal carboxylate structure. However, one of the reaction products is not yet fully characterized. The green compound of prob-able composition Mo2Xan4 mentioned earlier has a most puzzling behavior. Recent studies indicate that it reacts in the manner expected of an alkoxycarbonyl complex15, 16 and