Study of structure–mechanical heterogeneity of polyacrylonitrile-based carbon fiber monofilament by plasma etching-assisted radius profiling

Study of structure–mechanical heterogeneity of polyacrylonitrile-based carbon fiber monofilament by plasma etching-assisted radius profiling
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等离子体蚀刻辅助半径分析研究聚丙烯腈基碳纤维单丝的结构机械异质性

DOI:
10.1016/j.carbon.2016.12.037
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发表时间:
2017-04
期刊:
影响因子:
10.9
通讯作者:
Xiaodong He
Xiaodong He
中科院分区:
材料科学2区
文献类型:
--
作者:
Weicheng Jiao;Wenbo Liu;Rongguo Wang;Xiaodong He

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We present a feasible method, named as radius profiling, to study the structure–mechanical heterogeneity of polyacrylonitrile (PAN)-based carbon fibers (CFs). CF monofilaments were peeled layer by layer by plasma etching, and their electrical resistances and mechanical properties were measured by a multimeter and a single-filament tensile tester, respectively. The method allows the structure and mechanical properties of CF monofilament to be explored with high spatial resolution. The measurement results show that the modulus distribution along the fiber radius direction is highly dependent on the local crystallinity, and the maximums of both modulus and crystallinity appear at approximately 1.1–1.6 μm beneath the surface. The observation is used to explain the high modulus of PAN-based CFs.
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