Thermal rearrangement reactions of tricarbonyliron lactone complexes
Thermal rearrangement reactions of tricarbonyliron lactone complexes
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三羰基铁内酯配合物的热重排反应
DOI：
10.1039/p19820001355
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发表时间：
1982
期刊：
影响因子：
--
通讯作者：
D. Williams
中科院分区：
文献类型：
--
作者：
G. D. Annis;S. Ley;C. Self;R. Sivaramakrishnan;D. Williams
多种三羰基铁内酯配合物 (1)–(12) 在脱氧溶剂中加热后会发生热分解，产生脱羰、脱羧和重排途径产生的产物。反应产物通过光谱或X射线晶体学方法进行表征，或者在某些情况下通过独立合成进行表征。还提出了解释各种转变的机制。
A variety of tricarbonyliron lactone complexes (1)–(12) undergo thermal decomposition upon warming in deoxygenated solvents to give products arising from decarbonylation, decarboxylation, and rearrangement pathways. The products of the reactions were characterised by spectroscopic or X-ray crystallographic methods, or in some cases, by independent synthesis. Mechanisms to account for the various transformations are also proposed.