Photoactive barbiturate receptors: an ultimate lock-and-key system in which the key unlocks the lock.
Photoactive barbiturate receptors: an ultimate lock-and-key system in which the key unlocks the lock.
复制标题
光活性巴比妥酸盐受体：一种终极的锁钥匙系统，钥匙可以打开锁。
DOI：
10.1021/ol0700153
复制
发表时间：
2007
期刊：
影响因子：
5.2
通讯作者：
Kutateladze,AndreiG
中科院分区：
文献类型：
--
作者：
Lakkakula,Suman;Mitkin,OlegD;Valiulin,RomanA;Kutateladze,AndreiG
Conditional photofragmentation is achieved with binary systems incorporating the isophthaloyl bis-aminopyridine barbiturate recognition motif and dithiane- or trithiane-based photolabile modules, which cleave only in the presence of an external sensitizer. The components of the host−guest molecular recognition pair were each outfitted with either the sensitizer or the photocleavable module. In these pairs, photoinduced fragmentation is contingent on a molecular recognition event, which brings the sensitizer into the immediate proximity of the photolabile latch.
