A novel tellurophene-containing conjugated polymer with a dithiophenyl diketopyrrolopyrrole unit for use in organic thin film transistors

A novel tellurophene-containing conjugated polymer with a dithiophenyl diketopyrrolopyrrole unit for use in organic thin film transistors
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DOI:
10.1039/c3cc41250d
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发表时间:
2013-01-01
影响因子:
4.9
通讯作者:
Choi, Dong Hoon
Choi, Dong Hoon
中科院分区:
化学2区
文献类型:
--
作者:
Kaur, Matinder;Yang, Da Seul;Choi, Dong Hoon

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合成了一种新的碲基π共轭聚合物PDTDPPTe。PDTDPTe的光学带隙(E-g(opt)= 1.25 eV)小于噻吩基PDTDPPT(E-g(opt)= 1.30 eV)。包含PDTDPPTe的薄膜晶体管显示出优异的性能(μ(max)= 1.78 cm(2)V-1 s(-1),I-on/I-off = 10(5-6))。
A new tellurophene-based pi-conjugated polymer, PDTDPPTe, was synthesized. PDTDPPTe exhibits a smaller optical band gap (E-g(opt) = 1.25 eV) than thiophene-based PDTDPPT (E-g(opt) = 1.30 eV). Thin-film transistors comprising PDTDPPTe displayed outstanding performance (mu(max) = 1.78 cm(2) V-1 s(-1), I-on/I-off = 10(5-6)).