Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core.
Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core.
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DOI：
10.1002/anie.201203344
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发表时间：
2012-07
影响因子：
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通讯作者：
Liam Balloch;Jennifer A. Garden;A. Kennedy;R. Mulvey;T. Rantanen;Stuart D. Robertson;V. Snieckus
中科院分区：
文献类型：
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作者：
Liam Balloch;Jennifer A. Garden;A. Kennedy;R. Mulvey;T. Rantanen;Stuart D. Robertson;V. Snieckus
金属探测器：通过分离通常在串联官能化方法中隐藏的二锌化的2-取代噻吩中间体，发现了含有前所未有的16-原子[ZnC（3）]（4）“反冠”环的碗状纳米分子（见图; S黄，C灰，Zn蓝）。
Metal detector: a bowl-shaped nanomolecule (see picture; S yellow, C gray, Zn blue) containing an unprecedented 16-atom [ZnC(3)](4) "anti-crown" ring has been unearthed by isolating a dizincated 2-substituted thiophene intermediate that would normally be hidden in tandem functionalization methodology.