A Visible-Light-Mediated Synthesis of Carbazoles

A Visible-Light-Mediated Synthesis of Carbazoles
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DOI:
10.1002/anie.201306920
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发表时间:
2013-11-25
影响因子:
16.6
通讯作者:
Collins, Shawn K.
Collins, Shawn K.
中科院分区:
化学1区
文献类型:
--
作者:
Hernandez-Perez, Augusto C.;Collins, Shawn K.

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N-芳基和N-烷基咔唑的光合制备利用连续流动、可见光和原位形成的Cu基敏化剂(见图)。该方法是温和和有效的,并允许直接合成各种咔唑与不同的取代基,杂环,和复杂的碳结构。
The photosynthetic preparation of N‐aryl‐and N‐alkyl‐bearing carbazoles utilizes continuous flow, visible light, and an in situ formed Cu‐based sensitizer (see picture). The method is mild and efficient, and allows the straightforward synthesis of a variety of carbazoles with different substituents, heterocycles, and complex carbon architectures.