Synthesis and Characterization of Rare-Earth Metal Complexes Supported by 2-Imino or Amino Appended Indolyl Ligands with Diverse Hapticities: Tunable Selective Catalysis for Isoprene Polymerization
Synthesis and Characterization of Rare-Earth Metal Complexes Supported by 2-Imino or Amino Appended Indolyl Ligands with Diverse Hapticities: Tunable Selective Catalysis for Isoprene Polymerization
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具有多种触感的 2-亚氨基或氨基附加吲哚基配体负载的稀土金属配合物的合成和表征:异戊二烯聚合的可调选择性催化
DOI:
10.1021/acs.organomet.7b00575
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发表时间:
2017-09
期刊:
影响因子:
2.8
通讯作者:
Mu Xiaolong
中科院分区:
文献类型:
--
作者:
Zhang Guangchao;Wang Shaowu;Zhu Xiancui;Zhou Shuangliu;Wei Yun;Huang Zeming;Mu Xiaolong
The reaction of 2-(2,6-DippNHCH2)C8H5NH (Dipp = 2,6-iPrC6H3, C8H5NH = indolyl) with 1 equiv of (Me3SiCH2)3Yb(THF)2 at room temperature generated mononuclear ytterbium complex 1 having the indolyl ligands in η1:η1 mode with reduction of Yb3+ to Yb2+ and ox
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影响因子:
5.5
作者:
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通讯作者:
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影响因子:
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