The B−Mo (Boron-Molybdenum) system
The B−Mo (Boron-Molybdenum) system
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DOI：
10.1007/bf02881867
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发表时间：
1988-08
期刊：
影响因子：
--
通讯作者：
K. E. Spear;P. Liao
中科院分区：
文献类型：
--
作者：
K. E. Spear;P. Liao
图1显示了由[80Bre2]给出的经评估的Mo-B相图，由[81Spe]报告的热化学优化计算得到的图如图2所示。图1总结了图中的不变平衡；表2列出了文献中报道的所有不变平衡。为了构建图1，[80Bre2]主要使用来自[65Rud]和[77Sto]的实验数据，并从[67Por]获得支持信息。图3显示了在对[65Rud]的广泛研究中测定的实验熔点值，并指出了用于构建图1中的液线曲线的数据类型。图2中的液线曲线是使用来自组合热力学和相图数据的最优化的Gibbs能量函数来计算的，如下所述。
The assessed Mo-B phase diagram given by [80Bre2] is shown in Fig. 1, and the diagram calculated from the thermochemical optimization reported by [81Spe] is given in Fig. 2. The invariant equilibria from the diagrams are summarized in Table 1; Table 2 lists all invariant equilibria reported in the literature. To construct Fig. 1,[80Bre2] used experimental data primarily from [65Rud] and [77Sto], with supporting information from [67Por]. Figure 3 shows the experimental melting point values determined during the extensive study of [65Rud] and indicates the type of data used in constructing the liquidus curves in Fig. 1. The liquidus curves in Fig. 2 were calculated using Gibbs energy functions from an optimization of combined thermodynamic and phase diagram data [81Spe], discussed below.