Selective Hydrogen Production from Methanol with a Defined Iron Pincer Catalyst under Mild Conditions
Selective Hydrogen Production from Methanol with a Defined Iron Pincer Catalyst under Mild Conditions
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DOI：
10.1002/anie.201307224
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发表时间：
2013-12-23
影响因子：
16.6
通讯作者：
Beller, Matthias
中科院分区：
文献类型：
--
作者：
Alberico, Elisabetta;Sponholz, Peter;Beller, Matthias
分子定义明确的铁钳配合物促进甲醇水相重整为二氧化碳和氢气，这在甲醇和氢气经济的背景下是有意义的。第一次，地球丰富的铁配合物在温和的条件下，从醇有效的制氢证明。
Molecularly well-defined iron pincer complexes promote the aqueous-phase reforming of methanol to carbon dioxide and hydrogen, which is of interest in the context of a methanol and hydrogen economy. For the first time, the use of earth-abundant iron complexes under mild conditions for efficient hydrogen generation from alcohols is demonstrated.