The Renner effect and spin-orbit coupling
The Renner effect and spin-orbit coupling
复制标题
雷纳效应和自旋轨道耦合
DOI：
10.1080/00268976000100021
复制
发表时间：
1960
期刊：
影响因子：
--
通讯作者：
J. Pople
中科院分区：
文献类型：
--
作者：
J. Pople
Π 电子态线性三原子分子中振动电子相互作用的雷纳理论被扩展为考虑奇数电子自旋与电子轨道角动量之间的耦合。假设伦纳分裂和自旋轨道耦合能具有相同的数量级，但小于弯曲振动的能量子，得到了能级分裂和移动的摄动表达式。
The Renner theory of vibrational-electronic interaction in linear triatomic molecules in Π electronic states is extended to take account of coupling between an odd electron spin and the electron orbital angular momentum. Perturbation expressions for the splittings and shifts of energy levels are obtained on the assumption that the Renner splittings and the spin-orbit coupling energy are of the same order of magnitude, but less than the energy quantum of the bending vibrations.