SDC-Carbonate Composite Electrolytes for Low-Temperature SOFCs
SDC-Carbonate Composite Electrolytes for Low-Temperature SOFCs
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DOI：
10.1149/1.1960139
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发表时间：
2005-09
影响因子：
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通讯作者：
Jianbing Huang;Z. Mao;Lizhai Yang;R. Peng
中科院分区：
文献类型：
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作者：
Jianbing Huang;Z. Mao;Lizhai Yang;R. Peng
研究了基于钐掺杂的二氧化铈SDC -碳酸盐的混合物的新型复合材料用作在400-600°C下操作的低温固体氧化物燃料电池LTSOFC中的电解质材料。复合电解质在评价的温度下显示出高的离子电导率。组成和焙烧温度对复合电解质的形貌和电导率有很大影响。在燃料电池运行过程中，在两个电极上都观察到了水，这表明新的电解质材料同时传导氧离子和质子。从燃料电池的性能来看，这些复合电解质具有化学稳定性，在低温固体氧化物燃料电池的应用中具有诱人的前景。© 2005电化学学会。版权所有© 2018 - 2019 www.hzcn.com All Rights Reserved.
Novel composite materials based on mixtures of samarium-doped ceria SDC -carbonate were examined for use as electrolyte materials in low-temperature solid oxide fuel cells LTSOFCs operating at 400-600°C. The composite electrolytes showed high ion conductivity at evaluated temperatures. Composition and calcination temperature were found to affect the morphology and conductivity of the composite electrolytes greatly. During fuel cell operation, water was observed at both electrodes, indicating that the new electrolyte materials conduct both oxygen ions and proton simultaneously. According to fuel cell performance, these composite electrolytes are chemically stable, which is an attractive prospect in LTSOFC applications. © 2005 The Electrochemical Society. DOI: 10.1149/1.1960139 All rights reserved.