Tetrakis(tri‐tert‐butylsilyl)‐tetrahedro‐tetrasilane (tBu3Si)4Si4: The First Molecular Silicon Compound with a Si4 Tetrahedron

Tetrakis(tri‐tert‐butylsilyl)‐tetrahedro‐tetrasilane (tBu3Si)4Si4: The First Molecular Silicon Compound with a Si4 Tetrahedron
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四(三叔丁基甲硅烷基)-四面体-四硅烷 (tBu3Si)4Si4:第一个具有 Si4 四面体的分子硅化合物

DOI:
10.1002/anie.199310541
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发表时间:
1993
期刊:
影响因子:
--
通讯作者:
K. Polborn
K. Polborn
中科院分区:
--
文献类型:
--
作者:
N. Wiberg;C. Finger;K. Polborn

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黄橙子四(超硅基)-四面体-四硅烷(1),四面体-四硅烷Si 4 H 4的第一个衍生物,对热、光、水和空气稳定,在低于70 ℃的温度下不被钠还原,但与四氰基乙烯和溴等氧化剂反应。由反应(a)以57%的产率获得化合物1。
Yellow‐orange tetrakis (supersilyl)‐tetrahedro‐tetrasilane (1), the first derivative of tetrahedro‐tetrasilane Si 4 H 4, is stable to heat, light, water, and air, and is not reduced by sodium at temperatures below 70 C, but reacts with oxidants like tetracyanoethylene and bromine. Compound 1 was obtained in 57% yield from reaction (a).