Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated Ketones or Cyclopropyl Ketones with Hydrosilanes
Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated Ketones or Cyclopropyl Ketones with Hydrosilanes
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DOI：
10.1021/jo901513v
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发表时间：
2009-10-16
影响因子：
3.6
通讯作者：
Oshima, Koichiro
中科院分区：
文献类型：
--
作者：
Sumida, Yuto;Yorimitsu, Hideki;Oshima, Koichiro
α,β-不饱和酮和环丙基酮与氢硅烷在钯催化下发生氢化硅烷化反应，生成 (Z)-甲硅烷基烯醇化物。
alpha,beta-Unsaturated ketones and cyclopropyl ketones undergo palladium-catalyzed hydrosilylation with hydrosilanes to yield (Z)-silyl enolates.