High-performance copper alloy films for barrierless metallization

High-performance copper alloy films for barrierless metallization
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DOI:
10.1016/j.apsusc.2010.07.032
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发表时间:
2010-11
影响因子:
6.7
通讯作者:
C. Lin;W. Leau;C. H. Wu
C. Lin;W. Leau;C. H. Wu
中科院分区:
材料科学1区
文献类型:
--
作者:
C. Lin;W. Leau;C. H. Wu

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在这项研究中,我们观察到有用的特性V1.1-和V0.8N0.4轴承铜(Cu)薄膜沉积在无阻挡层的硅(Si)衬底上的共溅射工艺。Cu98.8(V0.8N0.4)或Cu(VNx)薄膜在700°C退火1h后电阻率低(2.9μΩcm),漏电流小,在Cu/Si界面没有发生可检测到的反应。这些观察结果证实了Cu(VNx)薄膜的高热稳定性。此外,由于这些膜具有良好的粘附特性,它们可以用于无阻挡层Cu金属化。
In this study, we observe useful properties of V1.1- and V0.8N0.4-bearing copper (Cu) films deposited on barrierless silicon (Si) substrates by a cosputtering process. The Cu98.8(V0.8N0.4), or Cu(VNx) for brevity, films exhibit low resistivity (2.9μΩcm) and minimal leakage current after annealing at temperatures up to 700°C for 1h; no detectable reaction occurs at the Cu/Si interface. These observations confirm the high thermal stability of Cu(VNx) films. Furthermore, since these films have good adhesion features, they can be used for barrierless Cu metallization.