Insertion of Imines into Vinylcyclopropanes Catalyzed by Nucleophilic Iron Complexes: A Formal [3+2]-Cycloaddition Strategy for the Synthesis of Substituted Pyrrolidine Derivatives
Insertion of Imines into Vinylcyclopropanes Catalyzed by Nucleophilic Iron Complexes: A Formal [3+2]-Cycloaddition Strategy for the Synthesis of Substituted Pyrrolidine Derivatives
复制标题
DOI：
10.1055/s-0034-1379180
复制
发表时间：
2014-09
期刊：
影响因子：
2
通讯作者：
Dominik Pursley;B. Plietker
中科院分区：
文献类型：
--
作者：
Dominik Pursley;B. Plietker
摘要 吡咯是多种生物活性分子的子结构。提出了一种通过将亚胺插入乙烯基环丙烷中直接铁催化合成吡咯的方法。以中等至良好的产率获得相应的吡咯。将讨论范围和限制。
Abstract Pyrrols are substructures in various biological active molecules. A straightforward iron-catalyzed synthesis of pyrrols via insertion of an imine into a vinylcyclopropane is presented. The corresponding pyrrols are obtained in moderate to good yields. Scope and limitations will be discussed.