An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission
An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission
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具有前所未有的 3D 异金属无机连接性和白光发射的无机-有机复合框架
DOI：
10.1039/c3cc38655d
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发表时间：
2013
影响因子：
4.9
通讯作者：
Du Shaowu
中科院分区：
文献类型：
--
作者：
Zhang Huabin;Lin Ping;Shan Xiaochen;Du Fenglei;Li Qipeng;Du Shaowu
具有 3D 无机 Cd-O-M (M = Cd, Rb) 连接性的无机-有机复合框架的第一个例子已经构建并进行了结构表征，该框架具有独特的 {Cd7Rb}n 螺旋和纳米级 {Cd16Rb4} 和 {Cd18Rb2} 环。该化合物表现出白光发射和波长依赖性光致变色响应。
The first example of an inorganic–organic composite framework with a 3D inorganic Cd–O–M (M = Cd, Rb) connectivity, featuring a unique {Cd7Rb}n helix and nanoscale {Cd16Rb4} and {Cd18Rb2} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.