New Radical Anion Complex, [(CH3)4N][Ni(dmit)2]2 with Metal-Semimetal Phase Transition
New Radical Anion Complex, [(CH3)4N][Ni(dmit)2]2 with Metal-Semimetal Phase Transition
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具有金属-半金属相变的新型自由基阴离子配合物，[(CH3)4N][Ni(dmit)2]2
DOI：
10.1246/cl.1987.1799
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发表时间：
1987
影响因子：
1.6
通讯作者：
H. Kobayashi
中科院分区：
文献类型：
--
作者：
Hyernjoo Kim;A. Kobayashi;Y. Sasaki;R. Kato;H. Kobayashi
测定了多硫π受体配合物[（CH 3）4 N][Ni（dmit）2]2的晶体结构，该配合物是由Ni（dmit）2（dmit=isotrithionedithiolate）分子和闭壳层阳离子组成的第一分子金属.金属-半金属转变具有较大的滞后。
The crystal structure determination was made on the multi-sulfur π-acceptor complex, [(CH3)4N][Ni(dmit)2]2, which is the first molecular metal composed of Ni(dmit)2 (dmit=isotrithionedithiolate) molecules and the closed-shell cations. The metal-semimetal transition with large hysteresis was observed.