Ionic Solvation in Aqueous and Nonaqueous Solutions

Ionic Solvation in Aqueous and Nonaqueous Solutions
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水溶液和非水溶液中的离子溶剂化

DOI:
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发表时间:
2001
期刊:
影响因子:
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通讯作者:
H. Ohtaki
H. Ohtaki
中科院分区:
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文献类型:
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作者:
H. Ohtaki

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总结。简要回顾了离子溶剂化的研究历史,讨论了溶剂化离子在水溶液和非水溶液中的结构和动力学性质。重点放在非水混合溶剂中的离子溶剂化,其中离子的优先溶剂化发生。提出了一个表示离子优先溶剂化程度的新参数。
Summary. The history of studies on ionic solvation is briefly reviewed, and structural and dynamic properties of solvated ions in aqueous and nonaqueous solutions are discussed. An emphasis is placed on ionic solvation in nonaqueous mixed solvents in which preferential solvation of ions takes place. A new parameter for expressing the degree of preferential solvation of an ion is proposed.