Degree of the Critical Isotherm

Degree of the Critical Isotherm
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DOI:
10.1063/1.1726135
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发表时间:
1964-09
影响因子:
4.4
通讯作者:
B. Widom
B. Widom
中科院分区:
化学2区
文献类型:
--
作者:
B. Widom

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本文提出了一个论点,它表明,如果g是临界等温线的度数,d是共存曲线的度数,f是当接近临界点时等温压缩系数变为无穷大的Δ Tc-T Δ-1的幂,则g=1+fd。讨论了这一结果与其他理论和实验事实的关系。
An argument is presented which indicates that if g is the degree of the critical isotherm, d the degree of the coexistence curve, and f the power of ∥ Tc—T ∥—1 with which the isothermal compressibility becomes infinite as the critical point is approached, then g=1+fd. The relation of this result to other theoretical and experimental facts is discussed.