Beyond Crystal Engineering: Significant Enhancement of C2H2/CO2 Separation by Constructing Composite Material

Beyond Crystal Engineering: Significant Enhancement of C2H2/CO2 Separation by Constructing Composite Material
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超越晶体工程:通过构建复合材料显着增强 C2H2/CO2 分离

DOI:
10.1021/acs.inorgchem.8b00341
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发表时间:
2018
期刊:
Inorg. Chem.
影响因子:
--
通讯作者:
Rajamani Krishna
Rajamani Krishna
中科院分区:
其他
文献类型:
--
作者:
Hui Qiong wu;Chang Sheng Yan;Feng Luo;Rajamani Krishna

文献摘要

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与已建立的提高气体分离性能的晶体工程方法不同,我们在这里展示了一种独特的方法。与原始的金属有机骨架(MOF)材料相比,由突破性计算得到的纳米AgNPs@Fe2O3@MOF复合材料的C2H2/CO2分离能力大大提高了2倍,在可见光照射下进一步放大了3倍。
Different from the established crystal engineering method for enhancing gas-separation performance, we demonstrate herein a distinct approach. In contrast to the pristine MOF (metal–organic framework) material, the C2H2/CO2separation ability for the resultant Ag NPs (nanoparticle)@Fe2O3@MOF composite material, estimated from breakthrough calculations, is greatly enhanced by 2 times, and further magnified up to 3 times under visible light irradiation.