Deposition and phase transformation behaviors of Ti-Ni-Hf-Cu quaternary shape memory alloy thin films

Deposition and phase transformation behaviors of Ti-Ni-Hf-Cu quaternary shape memory alloy thin films
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Ti-Ni-Hf-Cu四元形状记忆合金薄膜的沉积及相变行为

DOI:
10.1016/j.jallcom.2019.07.238
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发表时间:
2019
影响因子:
6.2
通讯作者:
Zhao Liancheng
Zhao Liancheng
中科院分区:
材料科学2区
文献类型:
--
作者:
Li Jun;Yi Xiaoyang;Meng Xianglong;Qiao Shi;Cai Wei;Zhao Liancheng

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In the present study, Ti–Ni-Hf-Cu thin films were successfully fabricated by magnetron sputtering process. Moreover, the effects of various factors on the quality of Ti–Ni-Hf-Cu thin film were investigated and the optimal processing parameters were determined. The results reveal that the composition and quality of Ti–Ni-Hf-Cu thin film can be mainly tailored by changing the sputtering power and Ar pressure. The amorphous Ti–Ni-Hf-Cu thin films with the high-quality can be obtained at the following condition: sputtering power = 150 W; Ar pressure = 0.6 Pa; sputtering time = 6 h. The annealed Ti–Ni-Hf-Cu thin film consisted of monoclinic B19′ martensite phase and nano-scale (Ti,Hf)2Ni type precipitate. Compared with the bulk Ti–Ni-Hf-Cu alloy, the annealed Ti–Ni-Hf-Cu thin film showed the lower martensitic transformation temperature. Nevertheless, the forward martensitic transformation starting temperature of the annealed Ti–Ni-Hf-Cu thin film was still higher than 100 °C, which can meet the requirement of the high temperature application field.