Poly{1,4-butanediammonium [tris-μ-oxalatodimanganese(II)] Hexahydrate}
Poly{1,4-butanediammonium [tris-μ-oxalatodimanganese(II)] Hexahydrate}
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聚{1,4-丁二铵[三-μ-草酸二锰(II)]六水合物}
DOI：
10.1107/s2414314616016394
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发表时间：
2016
期刊：
影响因子：
--
通讯作者：
H. Kitagawa
中科院分区：
文献类型：
--
作者：
M. Sadakiyo;T. Yamada;H. Kitagawa
在标题配位聚合物{(C4H14N2)[Mn2(C2O4)3]·6H2O}n中，MnII离子被草酸配体八面体配位，形成二维蜂窝状网络。这种阴离子骨架结合了中心对称的丁烷-1，4-二铵离子作为反阳离子。由于垂直结合的阳离子，二维网络略有扭曲。三种水分子位于层间空间，与骨架上的氨阳离子和草酸配体形成氢键。
In the title coordination polymer, {(C4H14N2)[Mn2(C2O4)3]·6H2O}n, the MnII ions are octahedrally coordinated by the oxalate ligands to form a two-dimensional honeycomb-like network. This anionic framework incorporates the centrosymmetric butane-1,4-diammonium ions as counter-cations. The two-dimensional network is slightly distorted as a result of the vertically incorporated cations. Three kinds of water molecules are located in an interlayer space, forming hydrogen bonds with the ammonium cations and the oxalate ligands of the framework.