Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands
Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands
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带有阴离子吡咯基 PNP 型钳配体的钛和锆二氮配合物的合成和反应活性
DOI：
10.1039/c8dt02739k
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发表时间：
2018
期刊：
影响因子：
--
通讯作者：
and Yoshiaki Nishibayashi
中科院分区：
文献类型：
--
作者：
Yoshiya Sekiguchi;Fanqiang Meng;Hiromasa Tanaka;Aya Eizawa;Kazuya Arashiba;Kazunari Nakajima;Kazunari Yoshizawa;and Yoshiaki Nishibayashi
制备了带有阴离子吡咯基 PNP 型钳配体的二氮桥联二钛和二锆配合物，并通过 X 射线分析对其进行了表征。研究了它们在温和反应条件下将氮气还原成氨和肼的催化活性。
Dinitrogen-bridged dititanium and dizirconium complexes bearing anionic pyrrole-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward reduction of nitrogen gas into ammonia and hydrazine under mild reaction conditions.