A facile synthesis of novel types of cyclodextrin derivatives by insertion of an aromatic dicarbonyl spacer into a permethylated α-cyclodextrin skeleton

A facile synthesis of novel types of cyclodextrin derivatives by insertion of an aromatic dicarbonyl spacer into a permethylated α-cyclodextrin skeleton
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DOI:
10.1039/b204960k
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发表时间:
2002-01-01
影响因子:
4.9
通讯作者:
Ikeda, I
Ikeda, I
中科院分区:
化学2区
文献类型:
--
作者:
Kida, T;Michinobu, T;Ikeda, I

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通过在全甲基化α-环糊精的骨架上插入一个芳香族二羰基间隔基,可以很容易地合成出新型的环糊精衍生物,并且插入间苯二甲酰的环糊精对对硝基苯酚的络合能力与全甲基化β-环糊精几乎相同。
Novel types of cyclodextrin derivatives are easily synthesized by the insertion of an aromatic dicarbonyl spacer into the skeleton of permethylated alpha-cyclodextrin, and the isophthaloyl-inserted one shows almost the same complexing ability toward p-nitrophenol as permethylated beta-cyclodextrin.