Synthesis and Properties of Regioregular Poly(3-substituted thiophene) Bearing Disiloxane Moiety in the Substituent. Remarkably High Solubility in Hexane

Synthesis and Properties of Regioregular Poly(3-substituted thiophene) Bearing Disiloxane Moiety in the Substituent. Remarkably High Solubility in Hexane
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DOI：
10.1246/cl.131222
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发表时间：
2014-01
期刊：
Chemistry Letters
影响因子：
1.6
通讯作者：
A. Mori;Kenji Ide;Shunsuke Tamba;S. Tsuji;Y. Toyomori;T. Yasuda
A. Mori;Kenji Ide;Shunsuke Tamba;S. Tsuji;Y. Toyomori;T. Yasuda
中科院分区：
化学4区
文献类型：
--
作者：
A. Mori;Kenji Ide;Shunsuke Tamba;S. Tsuji;Y. Toyomori;T. Yasuda

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以镍为催化剂，通过与脱氢溴剂或脱氢溴化剂的聚合反应，合成了具有3-取代基五甲基二硅氧烷结构的区域规则聚(3-取代噻吩基)衍生物。
Regioregular poly(3-substituted thiophene) derivative bearing pentamethyldisiloxane moiety at the 3-substituent is prepared by nickel-catalyzed polymerization reactions with dehydrobrominative or d...