The thermal unimolecular decompositions of C2H5Cl, i‐C3H7Cl, and t‐C4H9Cl
The thermal unimolecular decompositions of C2H5Cl, i‐C3H7Cl, and t‐C4H9Cl
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C2H5Cl、i-C3H7Cl 和 t-C4H9Cl 的热单分子分解
DOI：
10.1002/kin.550070615
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发表时间：
1975
影响因子：
1.5
通讯作者：
R. Jonas
中科院分区：
文献类型：
--
作者：
H. Heydtmann;B. Dill;R. Jonas
在0.1 ~ 300 torr的静态系统中，研究了氯乙酯、异丙基氯和叔丁基氯的热分解反应。得到了高压极限的Arrhenius方程：这三种单分子脱氯化氢反应的一阶速率常数（衰减）的压力依赖关系，从近似相等的ω值开始，通过适当选择温度，随着分子大小的增加而向低压转移；
The thermal decompositions of ethyl chloride, iso propyl chloride, and tertiary butyl chloride were studied in a static system in the pressure range of 0.1–300 torr. The following Arrhenius equations for the high‐pressure limit were obtained: The pressure dependence of the first‐order rate constant (falloff) for these three unimolecular dehydrochlorination reactions, starting with approximately equalkωvalues, by proper choice of temperature, is shifted to lower pressures with increasing molecular size: