Molecular Arrangement of Organized Molecular Films of Linear and Cyclic Amphiphilic Block Copolymers with Different Shapes
Molecular Arrangement of Organized Molecular Films of Linear and Cyclic Amphiphilic Block Copolymers with Different Shapes
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DOI：
10.14723/tmrsj.39.79
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发表时间：
2014-03
期刊：
影响因子：
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通讯作者：
Qi Meng;Masamichi Hashimoto;S. Honda;Y. Tezuka;Takuya Yamamoto;A. Fujimori
中科院分区：
文献类型：
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作者：
Qi Meng;Masamichi Hashimoto;S. Honda;Y. Tezuka;Takuya Yamamoto;A. Fujimori
采用丙烯酸丁酯和环氧乙烷组成的两亲线性嵌段共聚物和环嵌段共聚物，研究了“拓扑聚合物化学”这一聚合物科学中空气/水界面的新概念。这两种两亲共聚物在空气/水界面形成了相对稳定的单分子层。对两种共聚物在高温下的层状规律进行了估计，得到了两亲线性嵌段共聚物和环嵌段共聚物LB膜的温控面外x射线衍射（XRD）。不变，这意味着形成高度有序的规律性。
A "topological polymer chemistry" as a new concept in polymer science at the air/water interface is investigated by using amphiphilic linear and cyclic block copolymers consisting of butyl acrylate and ethylene oxide. The relatively stable monolayers of these two kinds of amphiphilic copolymers were formed at the air/water interface. two of copolymers estimate the layered regularity under high temperature, the temperature-controlled out-of-plane X-ray diffraction (XRD) of LB films of amphiphilic linear and cyclic block copolymers was obtained. unchanged, which means the formation of highly ordered regularity.