Response to Comment on "Investigation of the Iron-Peroxo Complex in the Fenton Reaction: Kinetic Indication, Decay Kinetics, and Hydroxyl Radical Yields".
Response to Comment on "Investigation of the Iron-Peroxo Complex in the Fenton Reaction: Kinetic Indication, Decay Kinetics, and Hydroxyl Radical Yields".
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对“芬顿反应中铁-过氧配合物的研究：动力学指示、衰变动力学和羟基自由基产率”的评论的回应
DOI：
10.1021/acs.est.8b00982
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发表时间：
2018
影响因子：
11.4
通讯作者：
Schmidt
中科院分区：
文献类型：
--
作者：
Wiegand;Kerpen;Schmidt
我们同意李等人的观点。（2018）1，并非所有数据都在研究的[H2O2]范围内表现出明显的平台期。然而，由于H2O2的强背景吸光度在很大程度上干扰了FeIII的吸光度，因此不可能在较高的[H2O2]下测定k '。事实上，我们已经尝试过用指数函数拟合数据来计算k13（方程a）。因此，k13可以通过外推到无穷大[H2O2]而导出。3 '=+× k k A e B
We agree with Lee et al.(2018) 1 that not all of our data exhibit clear plateaus within the investigated [H2O2] range. However, it was not possible to determine k’at higher [H2O2], due to the strong background absorbance of H2O2, which largely interfered with FeIII absorbance. Indeed, we already tried to calculate k13 by fitting our data with an exponential function (equation a). Thereby k13 can be derived by extrapolation to infinite [H2O2]. 3′=+× k k A e B