Dinuclear Palladium(I) Sandwich Complexes of Furan and Toluene
Dinuclear Palladium(I) Sandwich Complexes of Furan and Toluene
复制标题
呋喃和甲苯双核钯(I)夹心配合物
DOI：
10.1016/j.crci.2015.04.007
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发表时间：
2015
影响因子：
1.6
通讯作者：
T. Murahashi et al.
中科院分区：
文献类型：
--
作者：
K. Takijiri;K. Morita;T. Nakazono;K. Sakai and H. Ozawa;T. Murahashi et al.
双核钯配合物[Pd_2(CH_3CN)_6][X]_2(X=BF_4，Pf_6)与过量呋喃反应得到夹心型双呋喃双核钯(I)配合物[Pd_2(μ-呋喃)_2(CH_3CN)_2][X]_2。双钯夹心配合物中不稳定桥联呋喃的配体可以很容易地被甲苯取代得到双甲苯双钯(I)夹心配合物[Pd_2(μ-甲苯)_2(CH_3CN)_2][X]_2。
The reaction of a dinuclear palladium complex [Pd2(CH3CN)6][X]2(X = BF4, PF6) with excess furan afforded the sandwich-type bis-furan dinuclear palladium(I) complex [Pd2(μ-furan)2(CH3CN)2][X]2. The substitutionally labile bridging furan ligands in the dipalladium sandwich complex can be readily replaced with toluene to give the bis-toluene dipalladium(I) sandwich complex [Pd2(μ-toluene)2(CH3CN)2][X]2.