Solvent templated synthesis of metal?organic frameworks: structural characterisation and properties of the 3D network isomers {[Mn(dcbp)]DMF}n and {[Mn(dcbp)]2H2O}nElectronic Supplementary Information (ESI) available: figures and experimental data. See http://www.rsc.org/suppdata/cc/b3/b315483a/
Solvent templated synthesis of metal?organic frameworks: structural characterisation and properties of the 3D network isomers {[Mn(dcbp)]DMF}n and {[Mn(dcbp)]2H2O}nElectronic Supplementary Information (ESI) available: figures and experimental data. See http://www.rsc.org/suppdata/cc/b3/b315483a/
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DOI：
10.1039/b315483a
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发表时间：
2004-03
影响因子：
4.9
通讯作者：
E. Tynan;P. Jensen;P. Kruger;A. Lees
中科院分区：
文献类型：
--
作者：
E. Tynan;P. Jensen;P. Kruger;A. Lees
由Mn（II）和4，4 ′-二羧基-2，2 ′-联吡啶（H2 dcbp）形成的金属有机骨架的特性取决于合成中使用的主要溶剂，并产生稳健的网络异构体{[Mn（dcbp）]·1/2DMF}n，1和{[Mn（dcbp）]·2 H2O}n，2，它们具有非常不同的物理性质：1不可逆地结合DMF，而2可逆地结合水，同时保持结晶性。
The identity of the metal–organic framework formed by Mn(II) and 4,4′-dicarboxy-2,2′-bipyridine (H2dcbp) depends upon the predominant solvent employed in the synthesis and yields the robust network isomers {[Mn(dcbp)]·½DMF}n, 1, and {[Mn(dcbp)]·2H2O}n, 2, which possess vastly different physical properties: 1 irretrievably binds DMF, whereas 2 reversibly binds water whilst retaining crystallinity.