Synthesis of interlocked compounds utilizing the catalytic activity of macrocyclic phenanthroline-Cu complexes
Synthesis of interlocked compounds utilizing the catalytic activity of macrocyclic phenanthroline-Cu complexes
复制标题
利用大环菲咯啉-Cu配合物的催化活性合成联锁化合物
DOI：
10.1007/s10847-015-0511-1
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发表时间：
2015
影响因子：
2.3
通讯作者：
S. Saito
中科院分区：
文献类型：
--
作者：
Ryuto Hayashi;Yuichiro Mutoh;Takeshi Kasama;and Shinichi Saito;Hisashi Shimakoshi;松本有紗・吉田泰志・笠嶋義夫・三野孝・坂本昌巳;平岡 勇哉・池上 崇久・中村 幹夫・広光 一郎・吉岡大輔・御厨正博・片岡祐介・半田 真;S. Saito
发展了一种利用大环邻菲咯啉铜配合物的催化活性合成互锁化合物的新方法。大环邻菲咯啉-铜配合物被发现是几个偶联反应的良好催化剂，这种催化活性随后被用于合成[2]轮烷和[2]索烃。将催化穿线法与金属模板法相结合，合成了几种轮环十六烷。此外，通过在单环组分中进行两次螺纹反应，以良好的产率实现了[3]轮烷的一锅合成。
A new method for the synthesis of interlocked compounds utilizing the catalytic activity of macrocyclic phenanthroline–Cu complexes was developed. The macrocyclic phenanthroline–Cu complexes were found to be good catalysts for several coupling reactions, and this catalytic activity was subsequently utilized for the synthesis of [2]rotaxanes and [2]catenanes. By combining the catalytic threading approach with the well-known metal-template method, several rotacatenanes were synthesized. In addition, one-pot synthesis of [3]rotaxanes was achieved in good yield by performing the threading reaction twice in a one-ring component.