ENZYMATIC REGIOSELECTIVE ACYLATION OF HEXOSES AND PENTOSES USING OXIME ESTERS

ENZYMATIC REGIOSELECTIVE ACYLATION OF HEXOSES AND PENTOSES USING OXIME ESTERS
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DOI:
10.1039/p19920002891
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发表时间:
1992-11-07
期刊:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
影响因子:
--
通讯作者:
GOTOR, V
GOTOR, V
中科院分区:
其他
文献类型:
--
作者:
PULIDO, R;ORTIZ, FL;GOTOR, V

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己糖和戊糖已经用Amano PS和Candida anacutica(Novo SP435)脂肪酶,使用肟酯作为酰基供体酰化。该方法代表了游离戊糖的酶促酰化的第一个报告。该方法的选择性取决于起始材料的结构。
Hexoses and pentoses have been acylated with Amano PS, and Candida antarctica (Novo SP435) lipases, using oxime esters as acyl donors. This method represents the first report of the enzymatic acylation of free pentoses. The selectivity of the process depends on the structure of the starting material.