Synthesis and structural characterisation of stable cationic gold(I) alkene complexes
Synthesis and structural characterisation of stable cationic gold(I) alkene complexes
复制标题
DOI：
10.1039/b908109g
复制
发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Russell, Christopher A.
中科院分区：
文献类型：
--
作者：
Hooper, Thomas N.;Green, Michael;Russell, Christopher A.
[AuCl（PBu 3t）]与AgSbF6在CH2Cl2中在室温下在烯烃异戊烯、降冰片二烯、反式环辛烯以及有趣的是异丁烯的存在下处理，导致形成稳定的结晶络合物[Au（PBu 3t）（烯烃）][SbF6]，其特征在于通过NMR光谱和X射线晶体学。
Treatment of [AuCl(PBu3t)] with AgSbF6 in CH2Cl2 at room temperature in the presence of the alkenes norbornene, norbornadiene, trans-cyclooctene, and also interestingly, isobutylene, leads to the formation of stable crystalline complexes [Au(PBu3t)(alkene)][SbF6], characterised by NMR spectroscopy and X-ray crystallography.