SYNTHESIS AND CHARACTERIZATIONS OF NEAR INFRARED ABSORBING POLYMERS
SYNTHESIS AND CHARACTERIZATIONS OF NEAR INFRARED ABSORBING POLYMERS
复制标题
近红外吸收聚合物的合成与表征
DOI：
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发表时间：
2003
期刊：
影响因子：
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通讯作者：
Z. Wang
中科院分区：
文献类型：
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作者：
Y. Qi;P. Desjardins;Maria Birau;Xiangxiang Wu;Z. Wang
合成了一系列双核钌二羰基肼配合物[{Ru（bpy）2 } 2 μ-DCH] n +（其中bpy = 2，2 '-联吡啶，n = 2，3或4）. DCH-Ru络合物在NIR区域中是电致变色的，在1550-1600 nm处具有通常超过10000 M - 1 cm - 1的高吸收系数。还获得了具有良好的NIR电致变色性能的DCH-Ru络合物聚合物，并将其加工成用于在1550 nm波长处的光衰减的器件。这些DCH-Ru聚合物用于可变光衰减器的潜力已被证明与衰减功率在1550 nm的电信波长超过7.0 dB每微米的聚合物膜厚度。其他类别的NIR活性材料是并五苯二醌和相应的聚（醚并五苯二醌）。这些聚合物可以被电化学还原为在电信窗口（例如，1310 nm）。
A series of near infrared (NIR) absorbing dinuclear ruthenium dicarbonylhydrazine complexes (DCH-Ru), [{Ru(bpy) 2 } 2 μ-DCH] n + (where bpy = 2,2'-bipyridine and n = 2, 3 or 4), were prepared. The DCH-Ru complexes are electrochromic in the NIR region with a high absorption coefficient at 1550-1600 nm typically over 10000 M - 1 cm - 1 . DCH-Ru complex polymers with good NIR electrochromic properties were also obtained and processed to make a device for optical attenuation at a wavelength of 1550 nm. The potential of these DCH-Ru polymers for use in a variable optical attenuator has been demonstrated with an attenuating power at the 1550-nm telecommunication wavelength over 7.0 dB per micron of polymer film thickness. Other classes of NIR active materials are the pentacenediquinones and the corresponding poly(ether pentacenediquinone)s. These polymers can be electrochemically reduced to the corresponding semiquinone (radical anion) having NIR absorption within a telecom window (e.g., 1310 nm).