Raman spectrum of ammonia solid II
Raman spectrum of ammonia solid II
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氨固体拉曼光谱 II
DOI：
10.1063/1.451725
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发表时间：
1986
影响因子：
4.4
通讯作者：
F. Medina
中科院分区：
文献类型：
--
作者：
R. K. Luo;C. L. Nye;F. Medina
首次报道了固态氨在分子内和晶格区取向无序相II的拉曼光谱。分子内区域的光谱对于每个振动模式包含一条线，其被取向无序加宽。晶格区域包含两条靠近50和280 cm−1的宽线，归属于平移模式，以及两个归属于旋转弛豫的中心峰。
Raman spectra of the orientationally disordered phase II of solid ammonia in the intramolecular and lattice regions are reported for the first time. The spectrum of the intramolecular region contains one line for each vibrational mode, broadened by the orientational disorder. The lattice region contains two broad lines near 50 and 280 cm−1, assigned to translational modes, and two central peaks ascribed to rotational relaxation.