Highly enantioselective transfer hydrogenation of quinolines catalyzed by gold phosphates: achiral ligand tuning and chiral-anion control of stereoselectivity.
Highly enantioselective transfer hydrogenation of quinolines catalyzed by gold phosphates: achiral ligand tuning and chiral-anion control of stereoselectivity.
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DOI：
10.1002/anie.201204179
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发表时间：
2012-11
影响因子：
--
通讯作者：
Xi-Feng Tu;L. Gong
中科院分区：
文献类型：
--
作者：
Xi-Feng Tu;L. Gong
A little gold goes a long way: as little as 0.01 mol % of chiral gold phosphate is sufficient to afford the asymmetric transfer hydrogenation of quinolines with high stereoselectivity (up to 98 % ee). The achiral ligands on gold were found to have considerable effect on the catalytic efficiency.
