Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
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DOI：
10.3390/catal9080655
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发表时间：
2019-08-01
期刊：
影响因子：
3.9
通讯作者：
Sajiki, Hironao
中科院分区：
文献类型：
--
作者：
Ichikawa, Tomohiro;Matsuo, Tomohiro;Sajiki, Hironao
我们开发了一种微波介导的连续制氢方法，使用球形碳珠催化剂上的铂，从 2-PrOH 中连续制氢。催化剂盒由螺旋玻璃部分和直玻璃部分（螺旋-直盒）组成，是新开发的用于在 5% Pt/CB 存在下有效微波加热 2-PrOH。使用带有玻璃谐振调节管的螺旋直筒，在 2.4-2.5 GHz 范围内适当调节微波谐振。该反应仅通过10 W的单频微波照射进行，催化剂连续使用至少13 h，催化剂活性没有任何损失。
We developed a microwave-mediated continuous hydrogen production method from 2-PrOH using platinum on a spherical carbon-bead catalyst. The catalyst cartridge consisted of helical glass part, and straight glass part (helix-straight cartridge) was newly developed for the effective microwave heating of 2-PrOH in the presence of 5% Pt/CB. The microwave resonance was properly adjusted within 2.4-2.5 GHz using the helix-straight cartridge with the glass resonance-adjuster tube. The reaction was conducted by the irradiation of only 10 W of single-frequency microwaves and the catalyst was used continuously for at least 13 h without any loss of catalyst activity.