STUDIES OF AUSTRALIAN SOFT CORALS .35. THE TERPENOID CHEMISTRY OF SOFT CORALS AND ITS IMPLICATIONS
STUDIES OF AUSTRALIAN SOFT CORALS .35. THE TERPENOID CHEMISTRY OF SOFT CORALS AND ITS IMPLICATIONS
复制标题
DOI：
10.1016/s0040-4020(01)96476-2
复制
发表时间：
1985-01-01
期刊：
影响因子：
2.1
通讯作者：
TROTT, L
中科院分区：
文献类型：
--
作者：
COLL, JC;BOWDEN, BF;TROTT, L
在体内掺入甲羟戊酸内酯特别是到萜烯部分的倍半萜对苯二酚的软珊瑚Sinularia capillosa报道。Eudesma-4，7（11）-diene-8 β-醇（20）和相应的8-酮衍生物（21）是首次从软珊瑚（Nephthea species.在摄食软珊瑚Saracophyton trocheliophorum时采集到风成裸鳃类Phyllodesmium longicirra，发现已知的二萜trocheliophorol（25）集中在裸鳃类的角状体中。严格确定了trocheliophorol（25）的绝对立体化学，并表明是以前指定的光谱基础。
The in vivo incorporation of mevalonolactone specifically into the terpene portion of a sesquiterpene hydroquinone is reported for the soft coral Sinularia capillosa. Eudesma-4,7(11)-diene-8.beta.-ol (20) and the corresponding 8-keto derivative (21) were isolated from the soft coral (Nephthea species for the 1st time. The aeolid nudibranch Phyllodesmium longicirra was collected when feeding on the soft coral Saracophyton trocheliophorum, and the known diterpene trocheliophorol (25) was found to be concentrated in the cerata of the nudibranch. The absolute stereochemistry of trocheliophorol (25) was rigorously determined, and shown to be that previously assigned on spectroscopic grounds.