Immobilization of a Binuclear Ruthenium(III) Complex on a Gold (111) Surface: Observations of Proton-coupled Electron Transfer and Electrochemical Durability in Aqueous Media
Immobilization of a Binuclear Ruthenium(III) Complex on a Gold (111) Surface: Observations of Proton-coupled Electron Transfer and Electrochemical Durability in Aqueous Media
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DOI：
10.1246/cl.2006.1178
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发表时间：
2006-09
影响因子：
1.6
通讯作者：
Hiromitsu Uehara;M. Abe;Y. Hisaeda;K. Uosaki;Y. Sasaki
中科院分区：
文献类型：
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作者：
Hiromitsu Uehara;M. Abe;Y. Hisaeda;K. Uosaki;Y. Sasaki
在Au（111）电极上，通过自组装单层烷基链末端吡啶基的配位，将氧化桥接的钌（III）配合物固定在Au（111）电极上，固定的配合物在很宽的pH范围（2-12）内进行质子耦合电子转移反应，并具有良好的单层耐久性。
An oxo-bridged diruthenium(III) complex was immobilized on a Au(111) electrode through the coordination by terminal pyridyl groups of self-assembled monolayer of alkyl chains, and the immobilized complex underwent proton-coupled electron-transfer reactions in a very wide pH range (2-12) with remarkable monolayer durability for multiple potential cycles.