Star-like supramolecular polymers fabricated by a Keplerate cluster with cationic terminated polymers and their self-assembly into vesicles.
Star-like supramolecular polymers fabricated by a Keplerate cluster with cationic terminated polymers and their self-assembly into vesicles.
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DOI：
10.1039/c2cc33013j
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发表时间：
2012-06
影响因子：
4.9
通讯作者：
Qian Zhang;Lipeng He;Hui Wang;Cheng Zhang;Weisheng Liu;W. Bu
中科院分区：
文献类型：
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作者：
Qian Zhang;Lipeng He;Hui Wang;Cheng Zhang;Weisheng Liu;W. Bu
Keplerate簇合物[Mo（132）O（372）（CH（3）COO）（30）（H（2）O）（72）]（42-）与阳离子封端的聚苯乙烯静电结合，得到聚氧乙烯酸酯基超分子星星聚合物，该聚合物在CHCl（3）-MeOH混合溶剂中进一步自组装成囊泡聚集体.
The electrostatic combination of a Keplerate cluster, [Mo(132)O(372)(CH(3)COO)(30)(H(2)O)(72)](42-) with cationic terminated poly(styrene) yields polyoxometalate-based supramolecular star polymers, which can further self-assemble into vesicular aggregates in CHCl(3)-MeOH mixed solvent.