Anion exchange membranes (AEMs) based on poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and its derivatives
Anion exchange membranes (AEMs) based on poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and its derivatives
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DOI：
10.1039/c4py01671h
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发表时间：
2015-08
影响因子：
4.6
通讯作者：
J. Ran;Liang Wu;Yanfei Ru;Min Hu;Liang Din;T. Xu
中科院分区：
文献类型：
--
作者：
J. Ran;Liang Wu;Yanfei Ru;Min Hu;Liang Din;T. Xu
高分子阴离子交换膜在能源和环境等领域具有重要的应用价值，因而受到越来越多的关注。高性能AEM的最重要的先决条件是寻找合适的基础聚合物材料，其应该是化学稳定的并且易于处理以用于制造AEM。聚（2，6-二甲基-1，4-苯醚）（PPO）被认为是一个有前途的候选人，因为它使通用的路线，以获得高性能的AEM。此外，这些AEM的性能可以被可行地调节和控制，以满足各种应用要求。本文全面介绍了基于PPO的AEM的最新进展。在此，我们强调了用于设计基于PPO的AEM的策略，并希望为其他聚合物基AEM的合成提供有前途的原则，概念和路线。
Polymeric anion exchange membranes (AEMs) attract increasing attention, because they have prominent roles in various energy and environment-related fields. The most important prerequisite toward high performance AEMs is to search for an appropriate base polymeric material, which should be chemically stable and easily handled for fabricating AEMs. Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) is considered to be a promising candidate since it enables versatile routes to obtain high performance AEMs. Furthermore, the properties of these AEMs can be feasibly adjusted and controlled to meet various application requirements. In this review, recent advances in PPO based AEMs are comprehensively presented. Herein, we highlight the strategies used for designing PPO based AEMs and hope to provide promising principles, concepts, and routes into the synthesis of other polymer based AEMs.