Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling
Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling
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DOI：
10.1002/chem.201604452
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发表时间：
2016-11-01
影响因子：
4.3
通讯作者：
Rueping, Magnus
中科院分区：
文献类型：
--
作者：
Fan, Lulu;Jia, Jiaqi;Rueping, Magnus
本文首次报道了光氧化还原和镍催化C-O键断裂相结合的芳香磺酸酯脱羧氨甲基化反应。广泛的芳基三氟甲磺酸酯以及芳基甲磺酸酯、甲苯磺酸酯和烯基三氟甲磺酸酯以良好至优异的产率提供相应的产物。
A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C-O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.