Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes.
Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes.
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DOI：
10.1039/c3cc45823g
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发表时间：
2013-09
影响因子：
4.9
通讯作者：
Jun Zhang;Shangfei Song;Xiao Wang;J. Jiao;M. Shi
中科院分区：
文献类型：
--
作者：
Jun Zhang;Shangfei Song;Xiao Wang;J. Jiao;M. Shi
制备了三种带有主链单取代 CAAC 的钌配合物，与带有主链二取代 CAAC 的钌配合物相比，它们不仅在 RCM 反应中而且在油酸甲酯的乙烯醇分解中显示出催化效率的显着提高。
Three ruthenium complexes bearing backbone-monosubstituted CAACs were prepared and displayed dramatic improvement in catalytic efficiency not only in RCM reaction but also in the ethenolysis of methyl oleate, compared to those bearing backbone-disubstituted CAACs.