Breaking the Gordian Knot in the Structural Chemistry of Polyoxometalates: Copper(II)-Oxo/Hydroxo Clusters
Breaking the Gordian Knot in the Structural Chemistry of Polyoxometalates: Copper(II)-Oxo/Hydroxo Clusters
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DOI：
10.1002/chem.201605876
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发表时间：
2017-06-12
影响因子：
4.3
通讯作者：
Monakhov, Kirill Yu.
中科院分区：
文献类型：
--
作者：
Kondinski, Aleksandar;Monakhov, Kirill Yu.
这篇概念文章提供了对多氧铜酸盐（POCus）的分子设计和构建方面的见解，POCus是一类新兴的多氧铜酸盐（POM）样结构，具有低到高的核铜（II）-氧代/羟基骨架。POCus已经被确定为采用由早期过渡金属组成的经典POM的结构原理。它们的潜力，以负担图案的贵金属为基础的多金属氧酸盐被利用。引入“跨结构拓扑变换”来概括POCus和POM之间的骨架关系。这项研究为POCus的全新结构化学开辟了策略，这些化学与均相结构、药物化学、分子磁学和量子计算有关。
This Concept article provides insights into the molecular design and construction aspects of polyoxocuprates (POCus), an emerging class of polyoxometalate (POM)-like architectures featuring low-to-high nuclearity copper(II)-oxo/hydroxo skeletons. POCus have been identified to adopt the structural principles of classical POMs consisting of early transition metals. Their potential to afford motifs of the noble-metal-based POMs is exploited. "Cross-structural topological transformation" is introduced to generalize skeletal relationships between POCus and POMs. The study opens up strategies toward the brand-new structural chemistry of POCus with relevance to homogeneous photocatalysis, medicinal chemistry, molecular magnetism, and quantum computing.