Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
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DOI：
10.1371/journal.pone.0087192
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发表时间：
2014
期刊：
影响因子：
3.7
通讯作者：
Clark JH
中科院分区：
文献类型：
--
作者：
Parker HL;Rylott EL;Hunt AJ;Dodson JR;Taylor AF;Bruce NC;Clark JH
The metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticles is reported. This process eliminates the necessity for nanoparticle extraction from the plant and reduces the number of production steps compared to traditional catalyst palladium on carbon. These heterogeneous plant catalysts have demonstrated high catalytic activity in Suzuki coupling reactions between phenylboronic acid and a range of aryl halides containing iodo-, bromo- and chloro- moieties.
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